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Below is a shortlist just to make it easy to find all episodes.

Episode 168 : The New Captain Appears! His name is Amagai Shūsuke
Episode 169 : New Development, the Dangerous Transfer Student Appears!
Episode 170 : Desperate Struggle Under the Moonlit Night, the Mysterious Assassin and Zanpakutō
Episode 171 : Kenryū, the Profusion of Blooming Crimson Flowers
Episode 172 : Kibune Goes to War! The Violent Wind that Rages
Episode 173 : The Appearance of the Great Evil! The Darkness in the House of Kasumiōji
Episode 174 : Break the Mirror’s Boundary! Ichigo’s Captivity
Episode 175 : The Revenging Assassin, Ichigo is Targeted
Episode 176 : Mystery! The Sword-Consuming Assassin
Episode 177 : The Reversal of Rukia! The Rampaging Blade
Episode 178 : The Nightmare Which is Shown, Ichigo’s Inside the Mirror
Episode 179 : Confrontation?! Amagai vs. Gotei 13
Episode 180 : The Princess’ Decision, the Sorrowful Bride
Episode 181 : The 2nd Division Sorties! Ichigo is Surrounded
Episode 182 : Amagai’s True Strength, zanpakutō is released!
Episode 183 : The Darkness Which Moves! Kibune’s True Colors
Episode 184 : Kira and Kibune, Offense and Defense of the 3rd Division
Episode 185 : Ice and Flame! Fierce Fight of Amagai vs. Hitsugaya
Episode 186 : Sortie Orders! Suppress the House of Kasumiōji
Episode 187 : Ichigo Rages! The Assassin’s Secret
Episode 188 : Duel! Amagai vs. Ichigo
Episode 189 : The Fallen Shinigami’s Pride